期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 17, 页码 7204-7215出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo201339z
关键词
-
资金
- Ministry of Education, Science and Technology (MEST) [R01-2009-008-3940, 2010-0017149, 2010-0007737]
- NRF [K20802001473-10B120004500]
- National Research Foundation of Korea [2010-0007737, 2008-0061707, 2009-0063856] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Au(I)-catalyzed cyclization of alkenyl carbonyl compounds leading to a variety of substituted naphthalenes has been developed. This process exploits a dual function of the Au(I) catalyst: (1) the oxophilic nature of the Au(I) catalyst, counterintuitive to the pi-acidic reactivities generally associated with Au catalysts, and (2) olefin isomerization supported by the outcome of isotope scrambling experiments. It cannot be completely excluded that TfOH is a true operative catalyst in this protocol. In view of the practicality, the unnecessity of isomerically pure starting material in this reaction is particularly attractive and valuable.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据