期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 23, 页码 9792-9800出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo2018922
关键词
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资金
- NIGMS CMLD Initiative [P50 GM067041, P50 GM69663]
Photochemical oxa-di-pi-methane rearrangement of bicyclo[3.2.1]octanoid scaffolds affords multifunctional, donor acceptor cyclopropanes. A related photochemical reaction of an iminium ether substrate uncovered an unprecedented aza-di-pi-methane rearrangement of a beta,gamma-unsaturated iminium. Donor acceptor cyclopropanes have been evaluated as substrates for reactions generating several new chemotypes.
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