期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 16, 页码 6686-6693出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo201017w
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资金
- Australian government
We report the solid-phase total synthesis of the antifungal highly modified cyclic depsipeptide petriellin A. The synthesis confirms earlier reports on the absolute configuration of the natural product. The solid-phase approach resulted in a protected linear precursor, which was cleaved from the solid support prior to cyclization and final deprotection. Use of advanced coupling agents for several hindered amides was a feature of the synthesis. The natural product was prepared in overall 5% yield.
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