期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 9, 页码 3122-3130出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo1025805
关键词
-
资金
- Natural Sciences and Engineering Research Council of Canada
- Canadian Foundation for Innovation
- Ontario Innovation Trust
Synthetic methods for the preparation of maleimide and alpha,beta-unsaturated-gamma-butyrolactam compound collections are described. These routes take advantage of Pd cross-coupling and conjugate addition/elimination reactions to permit the facile production of bisaryl-maleimides, anilinoaryl-maleimides, and bisanilino-maleimides while allowing control over the synthesis of symmetrical or nonsymmetrical derivatives. Similarly, the chemistry developed allows for the generation of bisaryl substituted alpha,beta-unsaturated-gamma-butyrolactams. The scope and limitations of the approaches are presented.
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