期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 5, 页码 1185-1197出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo1024738
关键词
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资金
- National Science Foundation [CHE-9505868, CHE-9802823, CHE-0101021, CHE-0353541, CHE-0702734, CHE-1009038]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1009038] Funding Source: National Science Foundation
Organohypervalent iodine reagents have attracted significant recent interest as versatile and environmentally benign oxidants with numerous applications in organic synthesis. This Perspective summarizes synthetic applications of hypervalent iodine(V) reagents: 2-iodoxybenzoic acid (IBX), Dess-Martin periodinane (DMP), pseudocyclic iodylarenes, and their recyclable polymer-supported analogues. Recent advances in the development of new catalytic systems based on the generation of hypervalent iodine species in situ are also overviewed.
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