期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 7, 页码 1972-1978出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo102417x
关键词
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资金
- National Research Foundation, Singapore [NRF-RF2009-05]
- Nanyang Technological University
A cobalt-Xantphos-catalyzed, LiCl-mediated system has been developed for the direct and expedient preparation of arylzinc reagents in THF from the corresponding aryl iodides, bromides, and chlorides. Owing to the use of THF as a versatile solvent, the thus-formed arylzinc reagents displayed a high degree of compatibility with a variety of conventional as well as newly emerging metal-catalyzed cross-coupling reactions.
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