期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 9, 页码 3024-3033出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo200509m
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资金
- MEXT
- JSPS, Japan
- Grants-in-Aid for Scientific Research [22550101] Funding Source: KAKEN
The ortho-olefination of benzoic acids can be achieved effectively through rhodium-catalyzed oxidative coupling with alkenes. The carboxylic group is readily removable to allow ortho-olefination/decarboxylation in one pot. alpha,beta-Unsaturated carboxylic acids such as methacrylic acid also undergo the olefination at the beta-position. Under the rhodium catalysis, the cine-olefination of heteroarene carboxylic acids such as thiophene-2-carboxylic acid proceeds smoothly accompanied by decarboxylation to selectively produce the corresponding vinylheteroarene derivatives.
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