期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 22, 页码 9210-9215出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo201789k
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资金
- NIGMS [RO1 GM63540]
Ortho-quinone methides are important synthetic intermediates and widely implicated in biological processes. In this Synopsis, recent advances concerning the synthesis and utility of these intermediates are discussed with a particular emphasis on metal-catalyzed formation of quinone methide intermediates. Additionally, applications of these intermediates as partners in asymmetric synthesis will be discussed including methods we have developed that involve the enantioselective Pd-catalyzed formation of ortho-quinone methides and the trapping of aforementioned intermediates with diverse nucleophiles.
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