期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 7, 页码 2001-2009出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo1020322
关键词
-
资金
- National Natural Science Foundation of China [90713010]
- Ministry of Science and Technology of China [2009ZX09501-011]
A versatile and concise synthesis of N-alkylated 1,4-dideoxy-1,4-imino-D-arabinitol and 1,4-dideoxy-1,4-imino-L-xylitol derivatives is described. These were prepared using pseudohemiketal lactams as key intermediates, which in turn were obtained from sucrose. The key intermediates were prepared by a diastereospecific tandem reaction which facilitated the introduction of various substituents on the nitrogen atom of the iminosugars.
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