期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 5, 页码 1468-1471出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo102244x
关键词
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A new method for the synthesis of 2-aroyl-, 2-heteroaroyl-, and 2-cinnamoyl-substituted imidazoles in very good yields has been developed. The reaction employs novel nitrogen heterocyclic carbenes (NHCs), namely, N-arylamino-substituted NHCs, formed in situ from the corresponding imidazolium salts, and subsequent reaction with aromatic, heteroaromatic, and cinnamic aldehydes without utilizing transition metals or expensive specialized catalysts.
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