期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 7, 页码 2345-2349出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo200040x
关键词
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资金
- National Natural Science Foundation of China [20971041, 20803020]
- Chinese Ministry of Education [210146]
- Hunan Provincial Education Department [09B032, 09K081]
- Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Hunan University of Science and Technology
Active methylene compounds such as 5,5-dimethylcyclohexane-1,3-dione, cyclohexane-1,3-dione, 3-methyl-1-phenyl-1H-pyrazol-5 (4H)-one, 1,3-dimethyl-1H-pyrazol-5(4H)-one, and 3-methylisoxazol-5(4H)-one react with the 3-C position of N-confused porphyrin in THF for 5 min to afford a novel type of N-confused porphyrin 4 derivatives in good yield without the need of any catalyst.
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