期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 15, 页码 5985-5998出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo200340q
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资金
- Direction Generale de l'Armement
Anthrose is the upstream terminal unit of the tetrasaccharide side chain from a major glycoprotein of Bacillus anthracis exosporium and is part of important antigenic determinants. A novel entry to anthrose-containing antigens and precursors is described. The synthetic route, starting from D(+)-fucose, makes use of intermediates featuring a cyclic sulfite or sulfate function which serves successively as a protecting and a leaving group.
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