期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 13, 页码 5495-5501出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo200720c
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资金
- EPSRC
- GlaxoSmithKline [EP/E020712/1]
- Engineering and Physical Sciences Research Council [EP/E020712/1] Funding Source: researchfish
- EPSRC [EP/E020712/1] Funding Source: UKRI
The sequential use of Cu-catalyzed asymmetric allylic alkylation, olefin cross-metathesis, and Ir-catalyzed asymmetric allylic amination allows the concise, stereodivergent synthesis of complex chiral amines with complete regiocontrol and good diastereoselectivity, exemplified by the synthesis of a pair of diastereoisomeric unnatural branched amino acid derivatives.
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