期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 8, 页码 2716-2722出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo200071n
关键词
-
资金
- Swiss National Science Foundation
Using a two-step reduction/metalation procedure, highly stable chiral carbenium ions are transformed into reactive carbanion intermediates. Interesting polar ketone and thioamide products are the results of this umpolung that occurs with complete retention of configuration of the helical backbone.
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