期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 11, 页码 3855-3858出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo100352b
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资金
- MEXT
The ester-directed regioselective borylation of arenes catalyzed by a silica-supported monophosphine-Ir complex displayed a significantly broad substrate scope toward heteroaromatic compounds, including thiophene. pyrrole, furan, benzothiophene, benzofuran, indole, and carbazole derivatives. The regioselectivity is complementary to the selectivities observed in the heteroarene C-H borylation with the dtbpy-Ir catalyst system.
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