期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 19, 页码 6704-6707出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo101106k
关键词
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资金
- National Basic Research Program of China (973 Program) [2010CB833200]
- National Natural Science Foundation of China [20872055, 20972060]
- Specialized Research Fund for the Doctoral Program of Higher Education [20090211110007]
- 111 Project
The synthesis of several inherently chiral tribenzotriquinacenes (TBTQs) bearing one single mono- or difunctionalized aromatic nucleus and the optical resolution of one of these derivatives, a TBTQ-based salicylic acid (11), are described for the first time. Efficient access to enantio-pure, inherently chiral tribenzotriquinacenes may lay a foundation for studies of novel container compounds, supramolecular aggregation, chiral recognition, and asymmetric catalysis.
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