4.7 Article

Regioselective One-Pot Protection of D-Glucosamine

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JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 21, 页码 7424-7427

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AMER CHEMICAL SOC
DOI: 10.1021/jo101320r

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  1. National Science Council (NSC) [NSC 97-2113-M-001-033-MY3, NSC 98-2119-M-001-008-MY2, NSC 98-3112-B-007-005, NSC 98-2627-B-007-008]
  2. Academia Sinica

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A highly regioselective one-pot transformation of 2-azido2-deoxy-1,3,4,6-tetra-O-trimethylsilyl-D-glucopyranose via sequential additions of various reagents was systematically studied, yielding the fully protected derivatives and the 1-, 3-, 4-, as well as 6-alcohols, respectively.

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