期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 5, 页码 1779-1782出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo9025429
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资金
- ETH Zurich
1-Trifluoromethyl-1,2-benziodoxol-3-(1H)-one (1) is able to transfer the electrophilic CF3 group to the oxygen atom of THF in the presence of a Lewis or Bronsted acid. This results in a new ring-opening reaction of THF yielding trifluoromethyl ethers. Details of this reaction and the insight gained into the mechanism of action of reagent 1 are reported.
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