期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 21, 页码 7458-7460出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo101523k
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-
资金
- Korean government (MEST) [2009-0083533]
The concise and enantioselective synthesis of 15-deoxy-Delta(12,14)-prostaglandin J(2) (15d-PGJ(2)) has been accomplished in 11 steps from a known alcohol. The key step of the synthesis involves an asymmetric Rh-catalyzed cycloisomerization of ene-ynone, followed by an olefin isomerization.
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