期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 16, 页码 5697-5700出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo101127m
关键词
-
资金
- Long Island University
- University of Washington
Stabilization energies (SEH) of carbon radicals (R-center dot) are traditionally defined as the difference between the bond dissociation energy (BDE) of CH3-H, as a reference point, and of R-H. The term stabilization energy implies that it is an intrinsic property of the radical and a quantitative measure of stability. Applicable only to carbon-centered radicals, SEH stabilization energies are not transferable and cannot be used to estimate carbon-carbon BDE[R-R'], symmetrical BDE[R-R], or any other BDE[R-X]. SEH values by themselves are neither an intrinsic property nor a quantitative measure of stability. There is available an alternative that is not limited only to carbon-carbon and carbon-hydrogen bonds, does not depend on any one particular molecule or BDE as a reference point, and is accurate with several hundred different types of bonds.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据