期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 10, 页码 3511-3514出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo1004229
关键词
-
资金
- Chinese Academy of Sciences
- National Science Foundation [20772147, 20972179]
Experimental studies demonstrated that alcohols and amines can undergo a CF3COOAg-catalyzed nucleophilic addition at the outer C=N position of Ag(III) NCPs, leading to C-3-alkoxylated Ag(III) NCPs, which supports the computational result that the C=N bond on the periphery of Ag(III) NCPs is partially isolated from the 18 pi-electron macrocyclic conjugation system and is the active electrophilic center.
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