期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 2, 页码 510-513出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo902357x
关键词
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资金
- National Natural Science Foundation of China [20872163, 20732008, 20821002]
- Chinese Academy of Science
- Science and Technology Commission of Shanghai Municipality [08QH 14030]
- Major State Basic Research Development Program [2006CB806105]
An efficient access to N-phth pyrrroles via gold-catalyzed cycloisomerization of N-phth alkynylaziridines has been described. Functionalized pyrroles including pyrrole-2-carboxylates or 2-pyrrolyl ketone are easily constructed in generally good yields by this method. The resulting pyrroles can be further converted to N-amino pyrrole or 2-acyl pyrrole, which are important synthetic intermediates for amplification of molecular complexity.
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