期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 5, 页码 1550-1560出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo9022793
关键词
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A full overview of the decarboxylative cross-coupling reaction between heteraromatic carboxylic acids and aryl halides is described. This transformation employs palladium catalysts with short reaction times providing facile synthesis of aryl-substituted heteroaromatics. The effect of each reaction parameter including solvent, base, and additive employed as well as the full substrate scope of this transformation are reported. Mechanistic evidence is also disclosed that sheds light on possible reaction pathways.
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