期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 13, 页码 4337-4343出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo100857d
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- JSPS
A facile route to homoallyl alcohols bearing a trisubstituted double bond has been devised. The palladium-catalyzed reactions of aryl halides with the alcohols thus synthesized result in regiospecific allyl transfer from the alcohols to aryl halides via retro-allylation, providing allylarenes having two substituents at the 1 and 2 positions of the allyl moiety. Optically active homoallyl alcohols transfer their chirality at the hydroxylated carbon to the benzylic carbon of the product.
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