期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 9, 页码 3109-3112出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo902739n
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资金
- Research Council of the University of Tehran [27827/1/01]
An atom-economical phosphane-free palladium-catalyzed direct C-2 arylation of unactivated free NH-pyrroles is devised. This method provides a straithforward route to a wide variety of substituted 2-aryl-1H-pyrroles from readily accessible starting materials. Iodoarenes bearing electron-withdrawing and electron-donating substituents are tolerated under the presented reaction conditions. The scope of the reaction is also expanded to N-aryl and -alkylpyrroles albeit in lower yields.
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