期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 12, 页码 4224-4229出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo1008349
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资金
- MOST [2010CB833200]
- NSFC [20872054, 20732002]
The highly stereoselective syntheses of four diastereomers of natural 3,9,12-trihydroxycalamenene are described. The syntheses highlight the utility of an unusual framework of benzobicyclo[3.3.1] lactones, which were accomplished via an intramolecular Friedel Crafts-type Michael addition of alpha,beta-unsaturated lactones.
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