期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 5, 页码 2053-2058出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo802519b
关键词
-
资金
- CIAM [2005-C02-51833/A-1, SEP-2004-C01-45970/A1]
- FOMIX-GTO [GTO-2007-CO2-69094]
- Hong Kong Research Grants Council [603008]
- CONACyT
A series of 14 meso-polyarylamine-BODIPY (borondipyrromethene) hybrids of the general structure A were synthesized. Two methods were used to prepare them. The first protocol involved a direct Liebeskind-Srogl cross-coupling of thiomethylbodipys 1-2 with arylaminoboronic acids (4 examples, 75-98%). The second method involves a two-step sequence: a Liebeskind-Srogl reaction to prepare 6 meso-bromoarylbodipys (58-83%) followed by a Suzuki coupling of these Br-containing BODIPYs with arylaminoboronic acids (10 examples, 44-84%). Seven of these derivatives displayed emission in the near-infrared region. The optical properties of compound 18 were rationalized in terms of its crystal structure.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据