期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 17, 页码 6878-6880出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo901425z
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资金
- National Natural Science Foundation of China [20732003, 20872096]
- Ministry of Education [20070610019]
An efficient enantioselective Friedel-Crafts alkylation of indoles to ethyl glyoxylate catalyzed by chiral N,N'-dioxide-Sc(III) complex was developed. The corresponding 3-indolyl(hydroxy)acetates compounds were afforded in good yields with high enantioselectivities (up to 95% ee).
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