期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 23, 页码 8935-8938出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo902039a
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资金
- Skaggs Institute for Chemical Biology
A cinchona alkaloid-catalyzed, highly enantioselective, alpha-amination of oxindoles has been developed. The reaction is general, operationally simple, and affords the desired products in high yields with good to excellent enantioselectivity. Significantly, this Study provides a general catalytic method for the construction of a C-N bond at the C3 position of oxindoles as Well as for the creation of a nitrogen-containing, tetrasubstituted chiral center.
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