期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 16, 页码 6287-6290出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo9007892
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资金
- DST (the Department of Science and Technology), India
- UGC (the University Grants Commision)
IBX is readily reduced to IBA in the presence of molecular iodine in DMSO to generate hypoiodous acid (IOH). which reacts with a variety of olefins as well as alpha, beta-unsaturated ketones leading to their respective iodohydrins with anti stereochemistry. The same redox chemistry in acetonitrile containing TFA produces iodonium lolls for facile Iodination of a variety of aromatic compounds in respectable isolated yields.
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