期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 8, 页码 3207-3210出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo900141f
关键词
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A concise stereoselective route providing access to both enantiomers of the bioactive quinolizidine alkaloid lasubine II has been developed. The enantioselectivity was introduced by taking advantage of a proline-catalyzed asymmetric Mannich reaction. Next, the bicyclic system was constructed via a diastereoselective Mannich cyclization and subsequent ring-closing metathesis as the key steps.
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