期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 1, 页码 452-455出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8022022
关键词
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资金
- Direccion General de Investigacion del Ministerio de Ciencia y Tecnologia [CTQ2006-09323]
- Departamento de Educacion Universidades e Investigacion del Gobierno Vasco [IT-277-07]
- Ministerio de Ciencia e Innovacion
Aza-Michael reaction of ammonia, aliphatic, aromatic and optically active amines to an (alpha,beta-unsaturated imine derived from alpha-aminophosphonate affords (alpha-dehydroaminophosphonates with a gamma-stereogenic center bearing an amino group. Resulting gamma-amino alpha-dehydroaminophosphonates can be used for the preparation of phosphorylated pyrimidine derivatives.
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