期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 15, 页码 5568-5575出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo900943p
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资金
- Alma Mater Studiorum - Universita di Bologna (RFO funds)
Reactions between a superelectrophilic carbon reagent, 4,6-dinitrotetrazolopyridine, and 1,3,5-tris(N,N-dialkylamino)benzenes, a supernucleophilic carbon reagent series, afford C-C coupling products which are double sigma-complexes (W-M), Wheland-like on the 1,3,5-tris(N,N-dialkylamino)benzene moiety and Meisenheimer-like on the 4,6-dinitrotetrazolopyridine moiety. These complexes were moderately stable at low temperature, and they were characterized by NMR spectroscopy methods. H-1 NMR experiments at variable temperature strongly indicate that the formation of these complexes by a nucleophile/electrophile attack is a reversible process.
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