期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 15, 页码 5584-5589出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo9010365
关键词
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资金
- FAEP-UNICAMP
- FAPESP (Fundacao de Amparo a Pesquisa do Estado de Sao Paulo)
- CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico)
- INCT-INOFAR Proc. CNPq [573.564/2008-6]
The total synthesis of pteridic acids A and B is reported. The convergent asymmetric synthesis involved the use of a diastereoselective ethyl ketone aldol reaction followed by an efficient spiroketalization and provided pteridic acids A and B in 2.9% and 2.8% overall yield, respectively.
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