期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 10, 页码 3958-3961出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo802814r
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [18065008]
- Japan Society for the Promotion of Science and Technology
- Grants-in-Aid for Scientific Research [18065008] Funding Source: KAKEN
The reaction of an alpha-oxo acid chloride with an organostannane proceeds transition metal-catalyst-free to afford a 1,2-diketone in an excellent yield. In addition, a sequence comprising pretreatment of oxalyl chloride with an organostannane and a subsequent treatment with another organostannane also works as a convenient modification.
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