期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 13, 页码 4797-4803出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo900546k
关键词
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资金
- Okayama Foundation for Science and Technology
- NOVARTIS Foundation (Japan
- The Mitsubishi Foundation
- Japan Society for the Promotion of Science [19710184, 21710231, 16GS0206]
- Grants-in-Aid for Scientific Research [19710184, 21710231] Funding Source: KAKEN
Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastercomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.
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