期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 3, 页码 1397-1399出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo802372w
关键词
-
资金
- National Institutes of Health [GM58832]
- Merck Co., Inc.
The TunePhos/diamine-Ru(II) complex combined with t-BuOK in 2-propanol effectively catalyzes enantioselective hydrogenation of a wide range of simple ketones including aromatic, heteroaromatic, alpha,beta-unsaturated, and cyclopropyl ketones, affording high reactivity (up to 1 000 000 TON) and excellent enantioselectivities (>99% ee for 13 examples).
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