期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 23, 页码 9225-9228出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo9020826
关键词
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Enantioselective total synthesis of (-)-(S)-stepholidine, a drug candidate for the treatment of schizophrenia and/or drug abuse, is described. Asymmetric transfer hydrogenation of imines with use of Noyori's catalyst was used as the key step and (-)-(S)-stepholidine was synthesized in 6 steps, with 42% overall yield and > 99% ee.
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