期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 21, 页码 8064-8070出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo901183x
关键词
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资金
- Universita di Sassari (Fondo di Ateneo per lit Ricerca)
- University of Padova
We investigated the reducing properties of a series of 1,2-diaryl-1,2-disodiumethanes by means of equilibration reactions. The electron-donor power of these vic-diorganometals is strongly affected by the nature of substituents present either on the aromatic ring(s) or on the carbanionic centers, and it can be correlated with their ability to delocalize the arylmethyl carbanions. These findings are supported by electrochemical analysis of the reduction behavior of the parent 1,2-diarylalkene. Applications of these results to the reduction of selected substrates are described.
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