期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 6, 页码 2547-2553出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo802812w
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资金
- Spanish Ministerio de Educacion y Ciencia (MEC) [2010-CSD2007-00006, CTQ-2007-65218]
- Spanish MEC
The assembly of a wide range of dialkylzincs, cyclic enones, and chiral N-tert-butylsulfinyl imines in the presence of the appropriate phosphoramidite ligands allowed the formation of beta-amino ketones with three consecutive stereogenic centers in a stereocontrolled manner. The Baeyer-Villiger oxidation of the resulting amino ketones led to the corresponding aminolactones with excellent regio- and stereoselectivities.
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