4.7 Article

Trimethylsilyl Trifluoromethanesulfonate-Accelerated Addition of Catalytically Generated Zinc Acetylides to Aldehydes

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JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 7, 页码 2904-2906

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AMER CHEMICAL SOC
DOI: 10.1021/jo900102w

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  1. Thomas F. Jeffress and Kate Miller Jeffress Memorial Trust and Research Corporation

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In the presence of TMSOTf, a wide variety of terminal acetylenes add rapidly and efficiently to aldehydes via a catalytically generated zinc acetylide. In the absence of TMSOTf, no reaction is observed under otherwise identical conditions.

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