期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 12, 页码 4717-4720出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8003088
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Various anilides have been directly ortho-acetoxylated through a Pd(OAC)(2)-catalyzed C-H bond activation process. The amide group in anilides was found to functionalize as an elegant directing group to convert aromatic sp(2) C-H bonds into C-O bonds in high regioselectivity with acetic acid as the acetate source and K(2)S(2)O(8) as the oxidant.
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