4.7 Article

Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster

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JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 13, 页码 5147-5150

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AMER CHEMICAL SOC
DOI: 10.1021/jo800625v

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A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.

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