期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 14, 页码 5589-5591出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo800727s
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资金
- NIGMS NIH HHS [R01 GM046059, R37 GM046059, R37 GM046059-16, GM 46059] Funding Source: Medline
borylation of aryl halides with an inexpensive and atom-economical boron source, pinacol borane, has been developed. This system allows for the conversion of aryl and heteroaryl iodides, bromides, and several chlorides, containing a variety of functional groups, to the corresponding pinacol boronate esters. In addition to the increase in substrate scope, this is the first general method where relatively low quantities of catalyst and short reaction times can be employed.
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