期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 19, 页码 7803-7806出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo801544w
关键词
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资金
- Research Grants Council of Hong Kong [PolyU5006/05P, A-PG13]
- University Grants Committee [AoE/P-10/01]
This study describes a new class of indolylphosphine ligands, which can be easily accessed by a simple one-pot assembly from commercially available indoles, acid chlorides, and chlorophosphines. A combination of these three starting materials provides a high diversification of the ligand structure. The application of this ligand array in palladium-catalyzed Suzuki-Miyaura coupling reaction of aryl chlorides with arylboronic acids is described. A catalyst loading down to 0.01 mol % of Pd can be achieved.
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