期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 18, 页码 7260-7265出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo801151x
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资金
- University of South Florida
- University of Tennessee
- American Chemical Society
- National Science Foundation
- NSF [CRIF: MU-0443611]
The cobalt(II) complexes of D(2)-symmetric chiral porphyrins, such as 3,5-Di'Bu-ChenPhyrin P5, can catalyze asymmetric olefin aziridination with dipherylphosphoryl azide (DPPA) as a nitrene source. Acceptable asymmetric inductions were observed for the [Co(P5)]-based catalytic system, forming the desired N-phosphorus-substituted aziridines in moderate to high yields and good enantioselectivities.
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