期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 4, 页码 1639-1642出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo702429u
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[GRAPHICS] Asymmetric hydrogenation of allylic dimethylcarbinamide 2 with 1 mol % of cationic Rh(1)-Josiphos complex in THF under 500 psi of H(2) generated the corresponding tertiary carbinamide 1 in 98.5% assay yield and a 94:6 enantiomeric ratio. Upon crystallization, the product was isolated in 91% isolated yield and 95:5 enantiomeric ratio.
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