期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 4, 页码 1429-1434出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo702219f
关键词
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A new silane-promoted nickel-catalyzed amination of aryl chlorides with 0.5 mol % of Ni(acac)2, 1 mol% of 3,5,6,8-tetrabromo-1, 10-phenanthroline, and polymethythydrosiloxane was developed. A broad range of aryl and heteroaryl chlorides can be coupled with secondary amines and anilines to give the desired (het)arylamines in good to excellent yields. The reaction is sensitive to the nature and amount of the silane promoter.
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