期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 1, 页码 284-286出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo702024p
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资金
- NCI NIH HHS [5-T32-CA09112-30] Funding Source: Medline
- NIGMS NIH HHS [F31GM081905, GM58160, F31 GM081905-01] Funding Source: Medline
[GRAPHICS] The use of 3,4,7,8-tetramethyl-1,10-phenanthroline (Me-4-Phen) as a ligand improves the Cu-catalyzed cross-coupling reactions of aryl iodides and bromides with primary and secondary aliphatic, benzylic, allylic, and propargylic alcohols. Most importantly, by employing this catalyst system, the need to use an excessive quantity of the alcohol coupling partner is alleviated. The relatively mild conditions, short reaction times, and moderately low catalyst loading allow for a wide array of functional groups to be tolerated on both the electrophilic and nucleophilic coupling partners.
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