期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 14, 页码 5585-5588出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8005864
关键词
-
The second-order rate constant (k(2)) for the esterification of methoxyacetic acid with benzyl alcohol is reported in a range of ionic and Molecular solvents. The solvent effects on esterification rate are examined by using a linear solvation energy relationship based on the Kamlet-Taft solvent scales (alpha, beta, and pi*). It is shown that the hydrogen bond basicity of the solvent is the dominant parameter in determining the esterification rate and that the best rates are achieved in low basicity solvents.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据